Redeeming Qualities of Characters

Redeeming Qualities of Characters from â€Å"The Outcasts of Poker Flat† In â€Å"The Outcasts of Poker Flat†, each â€Å"immoral† character has redeeming qualities. Mother Shipping, a brothel owner, is the first to make the greatest sacrifice for another shows one of her redeeming qualities and her motherly nature. The Duchess, a prostitute, shows her redeeming qualities through being almost like an elder sister to Piney. And John Croakers, who despite his better knowledge of the situation, continues on with the group of outcasts and their young friends and continues to elf until his unexpected end.Despite their lowly characteristics, these three characters put forth amazing redeeming qualities which make them much higher than the hypocritical townspeople who banished them from Poker Flat. Mother Shipping is banished from Poker Flat for being a brothel owner. Despite this low standing part of her she has several redeeming qualities that redeem her from her past mistakes. The first redeeming quality she shows is her motherly nature toward not only Piney but the Duchess as well. Such as when she â€Å"requested Piney not to â€Å"chatter† (p. 88) when Piney said reckon now you're used to fine things at Poker Flat† (p. 88) this being her protecting the Duchess from embarrassment and protecting Pine's innocence. She also seems to show this side of her to Croakers as when she mentions that â€Å"el ‘didn't say ‘cards' once† during that evening† (p. 488) almost like a mother doting on the fact that her son had interest in something else besides his interest such as videotapes today, Sauerkraut's equivalent being card games. Another redeeming quality she has is her sacrificing herself for Pine's sake. At midnight on the tenth day she called Croakers to her side† (p. 490) and tells him that she is dying.She tells him not to â€Å"waken the kids† (p. 490) and take the bundle she is using as a pill ow. Within the bundle is her rations for the past week and she tells Croakers to ‘me to the (p. 490) and points at Piney. After she has done this she turns to the wall and passes away in her sleep quietly. This Mother Spittoon's top redeeming quality since she makes the greatest sacrifice for Piney and suffers for a week before dying Just for the young girl. This also plays into her quality f being motherly and trying to protect Piney by saving her rations for the girl knowing that they would not make it and run out food in due time.The Duchess is banished from Poker Flat for being a prostitute. Despite this immoral occupation she has several redeeming qualities. One of her redeeming qualities is that she protects Pine's innocence. She protects Pine's innocence by not telling her of what she was back in Poker Flat. She goes along with keeping the secret of not only her own past but Mother Spittoon's and Sauerkraut's when Croakers says mind out the truth about us all when they find out anything,† he added significantly, â€Å"and there's no good frightening them now† (p. 488).The Duchess's other redeeming quality is that she distracts Piney from their current situation so she won't be worried. She distracts the girl by directing â€Å"Piney in the rearrangement of the interior† of the cabin â€Å"with a taste and tact that opened the blue eyes of that provincial maiden to their fullest extent. † (p. 488). This action of the Duchess completely brings Pine's attention away from what is going outside and the events tit Uncle Billy and focuses her on the cabin and its furniture as well as the Duchess's knowledge of â€Å"fine things†.Croakers is banished from Poker Flat for gambling. One of Sauerkraut's much smaller redeeming qualities is when he insists on exchanging â€Å"his own riding horse, â€Å"Five Spot,† for the sorry mule which the Duchess rode. † (p. 485) so as to cheer not only her up but put the res t of the party into â€Å"closer sympathy' (p. 485), or a better mood. Another redeeming quality he has is that he stays with the party and â€Å"the thought of deserting his weaker and more pitiable companions never perhaps occurred to him. (p. 486) even though the others are all drunk and he, since drinking interferes with the mind, is completely sober. Another redeeming quality he has is that he doesn't think Billy has stolen their rides but he had instead â€Å"wandered from the camp and had accidentally stampeded the animals. † (p. 487). Another redeeming quality he has, which takes place in his past, is that he gave Tom back his money after a game of poker, or as he says â€Å"a â€Å"little game† which got him â€Å"some forty dollars† (p. 86) from the boy, but instead of keeping it he takes Tom and tells him o'er a good little man, but you can't gamble worth a cent. Don't try it over agar† (p. 486) and gives him his money back. Another redeeming quality Croakers has is that he gives Tom the snowshoes he has. Though Croakers could have used the shoes himself he â€Å"showed him the pair of snowshoes, which he had fashioned from the old pack-saddle. † (p. 490) and gives them to him telling the young man to use the shoes to save Piney to go to Poker Flat. Croakers even shows him the way far as the canon† (p. 90). Sauerkraut's final redeeming quality is that at the end even Hough he had made it he kills himself because the others had not, except for Tom, which made him â€Å"once the strongest and yet the weakest of the outcasts of Poker Flat. † Even though he had been strong through it all and had made it out of the cabin and got Tom to Poker Flat, he could not go on knowing that the others had died not just from the conditions but for each other and with nothing else to do, with nothing else in his hand, he ended the game that he called life.Mother Shipping, a brothel owner, makes the greatest sacrifice f or Piney and her motherly nature being her most distinguishing redeeming qualities. The Duchess, a prostitute, shows her redeeming qualities by protecting Pine's innocence and distracting her from the â€Å"streak of bad luck† the party came upon. And John Croakers, who despite his better knowledge of the situation, continues on with the group of outcasts and their young friends by staying with them, helping them, and not accusing others by what they had done in the past all the way up until his unexpected end which is another one of his redeeming qualities.Despite these characters lowly characteristics, these three put forth amazing qualities, actions which many could not have done, which make them much higher than the hypocritical townspeople who banished them from Poker Flat and cleanse them of their past mistakes allowing them all to pass on in peace which made it so that you could scarcely tell who had sinned.

Enhance the photocatalytic ability Essay Example

Enhance the photocatalytic ability Essay Example Enhance the photocatalytic ability Essay Enhance the photocatalytic ability Essay Abstraction The purpose of this undertaking is to heighten the photocatalytic ability of TiO2 by integrating an inorganic dye ( Ru ( bpy ) 32+ ) with strong seeable light soaking up belongingss into it. This should promote more hydroxyl groups to organize, get the better ofing one of the major disadvantages of TiO2, its inability to absorb in the seeable part. TiO2 and TiO2-Ru ( bpy ) 32+ were synthesised via the sol gel procedure. The burdens included 0, 0.1, 0.5, 1 and 2 % Ru ( bpy ) 32+ . The samples were calcined to 400, 600 and 800 A ; deg ; C. Characterisation of these samples was carried out utilizing the differential scanning calorimeter, x-ray diffraction, Raman, IR and emanation spectrometry. The DSC reported Ru debasement at 450 A ; deg ; C and showed that the dye was holding no consequence on crystal growing below 500 A ; deg ; C. XRD found that 100 % anatase had formed at both 400 and 600 A ; deg ; C and pure rutile was present at 800 A ; deg ; C. Its highlighted that at 700 A ; deg ; C, the anatase to rutile transmutation was speed uping by the increasing sums of Ru ( bpy ) 32+ being added. At 0, 0.1 and 0.5 % the % rutile nowadays was 11.1, 32.2 and 91.2 % severally. Raman analysis was carried out at two optical maser lines, 514.5 and 785 nanometer. The consequences reported at 514.5 nanometers identified the signifier of TiO2 at each calcination temp, which correlated the XRD consequences. The optical maser line at 785 nanometer was aimed at happening Ru extremums. The trouble here was the high fluorescence belongingss, low burdens and high possibility of combustion of the Ru composite. A extremum at 1360 cm-1 was found, nevertheless there is no literature available about the signifier of Ru ( bpy ) 32+ at these calcination temperatures, intending peak assignment was hard. Poor sample readying meant IR consequences were inconclusive and no information could be obtained from it. Diffuse optical density spectrometry calculated the set spread energy of TiO2 at 400, 600 and 800 A ; deg ; C to be 3.2, 3.2 and 3.0 electron volt severally. These values are consistent with the literature. Emission spectrometry was carried out between two scopes 360-600 nm and 480-800 nanometer to let analysis of both TiO2 and Ru ( bpy ) 32+ severally. The emanation spectrum of TiO2 reported a 22 nm displacement towards the seeable light part when TiO2 by itself and TiO2-2.0 % Ru ( bpy ) 32+ were compared at 600 A ; deg ; C. The technique, clip correlated individual photon numeration was used to measure the effects of temperature and the TiO2 environment on the life-time of the Ru stuff. Unheated Ru ( bpy ) 32+ had a long life-time of 557.8 Ns, which decreased to 1.5 Ns when the sample was heated to 400 A ; deg ; C. This important lessening suggests an aroused province negatron is traveling from the Ru ( bpy ) 32+ to the conductivity set of TiO2, therefore photosensitisation is happening. In look intoing the possibility that the stuffs synthesised may hold environmental redress belongingss, photocatalysis was set up. The sample was kept covered with a blue filter which ensured merely seeable light above 420 nanometers would make the sample. The mention, organic pollutant methylene blue degraded at 0.0001 min-1. The photocatalytic analysis of pure anatase showed a little betterment of 0.0002 min-1 under seeable visible radiation. A important betterment to 0.0015 min-1 in the rate of debasement seen at 0.5 % Ru ( bpy ) 32+ emphasised that at higher burdens more hydroxyl groups are produced doing the TiO2-Ru ( bpy ) 32+ stuffs a good campaigner for environmental redress. At 700 A ; deg ; C the acceleration of the anatase to rutile transmutation with increased concentrations of the dye is important. It shows that the Ru composite at this temperature was holding an consequence on the crystal growing of the nanocrystalline stuff. Besides the betterment in the photocatalytic ability of TiO2 when Ru ( bpy ) 32+ was added is of import as it ensures that the sample is now absorbing seeable visible radiation, doing it to bring forth more hydroxyl groups. Novel Photocatalytic Materials for Self- Cleaning Surfaces, 2010 Chapter 1: Introduction Novel Photocatalytic Materials for Self- Cleaning Surfaces, 2010 1. Introduction 1.1 Photocatalysis Photocatalysis is the soaking up of visible radiation by a stuff which consequences in the formation of hydroxyl groups ( A ; bull ; HO ) . ( 1 ) Depending on how efficient the production of these hydroxyl groups is will find how effectual the composite is in environmental redress. Hydroxyl groups are the most aggressive species generated in H2O with an oxidization valve of 2.80 V. ( 2 ) They attack most organic pollutants found in the atmosphere i.e. NOx and CH4. ( 3 ) This undertaking is based on the photocatalytic ability of TiO2, a semiconducting material with a UV visible radiation soaking up cut off at 390 nanometers. The set construction of a stuff is of import in measuring whether it is a good photocatalyst as it determines the light soaking up wavelength of the compound. Figure 1.1 illustrates this point good. TiO2 is an first-class photocatalyst as it remains stable even when it is photoexcited. ( 2 ) It is the anatase signifier of TiO2 that is best for photocatalysis, with a much stronger cut downing power than rutile as the CB is closer to the negative place. ( 2 ) TiO2 is already a proved success in many commercial merchandises such as ego cleansing glass, ( 4 ) anti fogging ( 5 ) and self cleaning surfaces ( 6 ) in infirmaries. By modifying TiO2 with a composite that has a strong seeable light soaking up it is possible that the photocatalytic ability will be improved. If successful more hydroxyl groups will be produced, therefore more organic pollutants will be degraded under normal seeable visible radiation. 1.2 Titanium dioxide TiO2 is found in nature in three polymorphous signifiers anatase, rutile and brookite. Brookite is rather rare and hard to fix hence the anatase ( 3.2 electron volt ) and rutile ( 3.0 electron volt ) signifiers are most common. ( 5 ) TiO2 has a d0 negatron constellation which explains its white visual aspect and inability to absorb seeable visible radiation. The set spread energy of a semiconducting material is of import as it a ) determines the optical soaking up of the stuff and B ) high spots issues that may originate due to recombination. ( 2 ) It is seen that at 3.0 and 3.2 electron volts TiO2 can merely absorb UV visible radiation. Merely 3-5 % of the solar spectrum making the Earth is UV visible radiation restricting the photocatalytic ability of TiO2 instantly. ( 8 ) Besides the rutile signifier has a disadvantage in that it has a higher recombination rate than that of anatase. Figure 1.2 high spots the ability of TiO2 to partake in environmental redress. The soaking up of a photon of light below 390 nm promotes and negatron from the valency set to the conductivity set go forthing an negatron deficient ( h+ ) at the valency set. An oxidization reaction is promoted here. The excess negatron now present in the conductivity set of TiO2 encourages a decrease reaction. ( 9 ) Ohio groups are being produced at each set and it is the concentration/efficiency in the production of these that will make up ones mind whether environmental redress is an option or non. Unfortunately, the efficiency of TiO2 in hydroxyl extremist production exists merely in the UV part. Therefore unmodified TiO2 has a limited consequence on environmental redress. 1.3 TiO2-Ru ( bpy ) 32+ In the past TiO2 has been modified with Ag, ( 8 ) Fe, ( 10 ) and N. ( 11 ) Each dopant was found to impact some belongings of the nanocrystalline stuff. Seery et al described how TiO2-Ag improved both the photocatalytic public presentation of TiO2 and enhanced its anti bacterial effects. The Ag atoms acted as a trap for the CB negatrons leting the efficiency of hydroxyl extremist production to be increased. ( 8 ) Fe, a group 8 component was found to speed up the anatase to rutile transmutation. and nitrogen doping resulted in an active wavelength scope below 520 nanometers, significant in leting TiO2 to organize hydroxyl groups under seeable visible radiation. This undertaking proposes that modifying TiO2 with an inorganic dye which has a strong seeable light soaking up may excessively help photocatalytic activity in the seeable part. Therefore the complex tris ( 2,2-bipyridyl ) dichloro-ruthenium ( II ) hexahydrate ( 12 ) with an soaking up of 450 nanometer was suggested.8 The construction of the dye is three bidentate bipyridine ligands attached to a Ru metal composite. It is hoped that the rule behind Gratzel s dye sensitised solar cells can be imitated slightly so that dyesensitisation occurs between the TiO2 substrate and the inorganic dye. The dye must absorb seeable visible radiation, promote an negatron to the aroused province and reassign the aroused negatron to the CB of TiO2 where decrease reactions occur, bring forthing hydroxyl groups. Ru ( bpy ) 32+ a d6 metal ion has an intense MLCT which has the possible to advance charge injection processes to the conductivity set of broad set spread semi music directors like TiO2, SnO2 and ZnO. ( 13 ) ( Figure 1.3 ) If successful TiO2-Ru ( bpy ) 32+ can be developed in environmental redress as the more hydroxyl groups produced the more of the organic pollutant that is degraded. In Ireland the chief green house gas is methane. ( 14 ) The pollutant produced mostly in agribusiness has a OH sink. If TiO2-Ru ( bpy ) 32+ proves a success, Ireland s part to green house gases can be significantly decreased by merely fixing pigments integrating the TiO2-Ru ( bpy ) 32+ stuffs. ( Figure 1.4 ) These pigments may so be painted onto the outside of sheds on farms and even onto farm machinery in a command to see a lessening in Ireland s agribusiness methane concentration. A technique similar to this by a company called Pilkington was a immense success where they produced thin movies and coated them onto the sides of glass edifices where they degraded soil etc. ( 6 ) In other words the glass was self maintained. ( Figure 1.5 ) 1.4 Synthesis via colloidal suspension gel procedure A simple wet chemical technique illustrated below in figure 1.6. The method was used by Seery et Al in modifying TiO2 with Ag. ( 8 ) It enables unvarying scattering of atoms in a gel. Acetic acid was used to give the connection molecules strength as it ensures strong adhering between Ti-O. The precursor TTIP enables TiO2 formation and H2O makes it a liquid gel. 1.5 Purposes The overall purpose of this undertaking is to heighten the seeable light activity of TiO2. By adding Ru ( bpy ) 32+ into the semiconducting material, synthesizing it via the sol gel procedure a displacement in photocatalytic activity from the UV to the seeable part is predicted, similar to that seen in N and Ag doped systems. The intent of this is to enable the semiconducting material to breakdown organic pollutants both indoors and out-of-doorss by holding the ability to map under seeable visible radiation. The undertaking has three subdivisions synthesis, word picture and photocatalysis. The synthesis of TiO2 modified with Ru ( bpy ) 32+ was done utilizing the sol-gel procedure. This is a simple, yet effectual technique to integrate the dye into TiO2. Characterizing the prepared TiO2 samples is of import as this is the first effort at utilizing this combination via a sol gel procedure. Techniques such as XRD and Raman will place the nature of TiO2, UV/vis and emanation spectrometry will assist find the set spread energies of the samples and will guarantee that the presence of the other ingredient is non impacting their characteristic emanation values. The photocatalytic ability of the prepared samples must besides be investigated ; and will reflect if the sample s debasement rate has improved under seeable visible radiation. A photocatalysis workstation must be set up to include a 60 W lamp, stirring equipment and a composition board box, the organic pollutant impersonator methylene blue is to be used as it is in stock. A bluish filter is a important add-on as it suf ficiently ensures merely light above 420 nm reaches the sample. TCSPC evaluates by what procedure the organic debasement may happen i.e. if dyesensitisation is happening a decrease in the life-time will happen between modified and unmodified TiO2. If an betterment is found the stuff may be so suggested as a possible campaigner for future environmental redress techniques. Chapter 2: Experimental 2. Experimental 2.1 Materials Titanium ( IV ) isopropoxide ( 97 % ) , acetic acid ( 99.8 % ) and tris ( 2,2bipyridy ) dichloro Ru ( II ) hexahydrate [ Ru ( bpy ) 32+ ] pulverization were all purchased from Sigma Aldrich. Methylene blue was obtained from Gurrs Co. All chemicals used as received. Distilled H2O was used in all phases of synthesis, word picture and photocatalysis. 2.2 Synthesis 2.2.1 Preparation of TiO2 The synthesis was carried out in the fume goon as it contained acetic acid. Acetic acid ( 48 milliliter ) was placed in a big beaker and set stirring. Titanium ( IV ) isopropoxide ( 25 milliliter ) was added into the solution dropwise organizing a thick gel. A glass stirring rod was used to blend the gel until stirring saloon was free to travel once more. Distilled H2O ( 150 milliliter ) was added to the solution dropwise, leting a clear syrupy solution to organize. The solution was left stirring for an hr and placed in an oven overnight at 100 A ; deg ; C. 2.2.2 Preparation of TiO2 Ru ( bpy ) 32+ The synthesis was carried out in the fume goon as it contained acetic acid. Acetic acid ( 48 milliliter ) was placed in a big beaker and set stirring. Pre-weighed Ru ( bpy ) 32+ pulverization ( 0.1, 0.5, 1.0 and 2.0 % ) , table 2.2 was added to acetic acid. Titanium ( IV ) isopropoxide ( 25 milliliter ) was added dropwise to the solution, a thick gel formed. A glass stirring rod was used to blend the gel until stirring saloon was free to travel once more. Distilled H2O ( 150 milliliter ) was added dropwise to the mixture and a reddish-orange syrupy solution formed. After stirring for one hr the solution was placed in an oven overnight at 100 A ; deg ; C. A pulverization formed changing in coloring material from light orange to deep ruddy depending on Ru ( bpy ) 32+ concentration. 2.2.3 Calcination of dried TiO2 samples The pulverizations were calcined in the Carbolite furnace leting temperatures of up to 1200 A ; deg ; C. Approximately 1 g of sample was ground down in a pester and howitzer and placed in a crucible. The melting pots were labelled saying the concentration and coveted calcination temperature of the pulverization and its location in the furnace was besides noted as labelling tended to be removed at these high temperatures. The P button on the furnace was pressed and 5.0 A ; deg ; C / min selected. The button was pressed once more and pl appeared on the screen leting a temperature alteration. The button was held in and palladium selected to put the tally continuance. Calcination of samples occurred by pressing run . Samples calcined at 400, 600, 700 and 800 A ; deg ; C each for 2 H periods. 2.3 Word picture 2.3.1 Differential scanning calorimeter The Rheometric scientific derived function scanning calorimeter must honk twice, bespeaking it is on and working decently. The RSI orchestrator icon on the desktop was clicked on. The icon upload was selected on the left of the screen. When it turned green the drama icon selected. The pressing edit trial the parametric quantities were set as follows, 25 500 A ; deg ; C, raging at 10 A ; deg ; C / min. When the system beeped four times it began coolingto 25 A ; deg ; C and so ramped from at that place. Excel data format was used by salvaging as export under file and salvaging as a txt . Then it could be imported into Excel. A clean mention sample and the land down analyte was placed in two separate DSC holders and inserted into the analysing chamber by raising off the palpebra and taking the two rings underneath. The mention was placed on the right and the analyte on the left. Ringss and palpebra replaced and analysis initiated. Run clip was approx. 42 min and so consequences were exported and imported into Excel plotting heat flow ( mW ) against temperature ( A ; deg ; C ) . 2.3.2 X-ray diffraction The pulverizations were characterised utilizing X-ray diffraction ( XRD ) , the Siemens D 500 X-ray diffractometer with the diffraction angles scanning from 2q = 20 80 A ; deg ; , utilizing a Cu Ka radiation beginning. There are two procedures available to XRD, double sided gluey tape or mix with propanone. For word picture of these samples double sided gluey tape was used. The tape was placed on a glass slide ( glass is formless therefore it will non interfere with the analysis ) . The calcined pulverization was ground down utilizing a pestler and howitzer. The sample was so spread out over the gluey tape. The slide was held up to the visible radiation to guarantee no light incursion was happening. Sample was placed in analysis chamber and set running. All information imported into Excel and plotted strength against 2? . The % anatase to rutile was calculated utilizing equation 2.2 below. Equation 2.2 To cipher % anatase to % rutile in a sample ( 8 ) Wr=11+ 0.8 ( 1A1R ) Wr = fraction rutile, 1A = contemplations of anatase, 1R = contemplations of rutile 2.3.3 IR spectrometry The Perkin-Elmer -spectrum 100 FTIR was used for infrared ( IR ) analysis. All samples were prepared as phonograph record in a 1:10 ratio, sample: KBr. These phonograph records were placed between labelled beds of tissue paper during analysis, cut downing wet consumption. Each phonograph record was placed in the IR holder and inserted into the analysis chamber of the instrument. Under the start icon, spectrum selected. The username and watchword were obtained and entered. A background spectrum obtained utilizing the prepared KBr phonograph record, mention. The scan scope was set, 450 4000 cm-1. The analyte was placed in the analysis chamber and the scan icon was selected. When finished the extremums were labelled utilizing the nomadic precursor on the screen. The consequences were originally saved into pigment by pressing print screen on the keyboard and choosing paste in the pigment plan. Subsequently they were saved as an ASCII file and imported into Excel, plotting % transmission against wavenumber ( cm-1 ) . 2.3.4 Raman spectrometry Raman spectroscopic analysis was carried out on two optical maser lines 514.5 and 785 nanometer because 514.5 nanometers merely detected TiO2 extremums. The S.A. ( Jobin Yvon ) LabRam 1B with an argon ion gave a optical maser wavelength of 514.5 nanometers at 50 mW, and the Horiba Jobin Yvon LabRAM HR 800, provided a optical maser line wavelength of 785 nanometers which aimed to enable Ru ( bpy ) 32+ sensing. The instruments were already calibrated during line alteration therefore analysis commenced instantly. Sample readying included puting a little sum of land pulverization onto a microscope slide while flattening it every bit much as possible with the dorsum of a spatula before puting it under the microscope. System set up by turning the key in the optical maser box at the rear of the instrument to on . A green or violet laser line was observed for 514.5 and 785 nanometer severally. The lab spec icon on the desktop was selected and the parametric quantities were set. The scope was set at 100 4000 cm-1 while temperature was varied. The camera and lamp were switched on and a level country was found and highlighted for optical maser irradiation seting concentrate wheel if necessary. Magnification was 10X. A smooth country highlighted for sample irradiation guaranting equal optical maser incursion. For analysis, both the camera and visible radiation were turned away and the optical maser was switched on. Analysis initiated by pressing the hog icon on the toolbar bill of fare. All informations saved in extra as labspec. [ tsf ] and txt so converted and imported into Excel for coverage, plotting strength against wavenumber ( cm-1 ) . The undermentioned parametric quantities were set, clip 5 s and the optical maser filter varied due to the grade of fluorescence and combustion of the Ru sample was unknown. A technique recommended to place the extent of combustion was enlightening the sample with the optical maser for approx 30 s and so analyzing the sample under the microscope placing burn forms and to what grade. 2.3.5 Diffuse optical density spectrometry The technique desired to find the set spread energy of each sample was diffuse coefficient of reflection spectrometry nevertheless, it was non working hence diffuse optical density substituted it. Analysis was carried out utilizing the Perkin Elmer Lambda 900 UV/VIS/NIR Spectrometer between 400 800 nanometer. None of the TiO2 modified samples gave reportable consequences utilizing this technique. Therefore, emanation spectrometry had to be used alternatively to find the set spread energies. Equation 2.3 below was used to find the set spreads of the pure TiO2 samples. Equation 2.3 Formula to cipher set spread energy ? E=1238.9? 2.3.6 Emission spectrometry The Perkin Elmer LS55B Luminescence Spectrometer was used to find the set spread energies utilizing equation 2.3. Approx 20 milligram of sample was placed in a 10 milliliter volumetric flask and made up to the grade with distilled H2O. All volumetrics were placed in a sonicator for 15 min to guarantee unvarying scattering. Dispersions were each placed in a 4 sided vitreous silica cuvette to undergo luminescence. On the desktop the icon Fn Winlab was selected. From the option list scan mth was clicked. The parametric quantities were set between 360 600 nanometer, ? ex = 330 nanometers analyzing for TiO2 and 480 800 nanometer, ? ex = 450 nanometer for Ru ( bpy ) 32+ analysis. The consequences were imported into Excel, plotting strength versus wavelength ( nm ) . The? soap was highlighted for TiO2 emanation consequences and was used to find the set spread energy of the stuff, equation 2.3. These consequences were besides used in puting the parametric quantities for TCSPC. 2.3.7 Time Correlated Single Photon Counting ( TCSPC ) These emanation values were besides used to help lifetime values of the samples utilizing the clip correlated individual photon numeration spectrometer ( TCSPC ) FL900. The spread samples in 2.3.6 above were re-used to obtain the life-times of the samples. The instruments parametric quantities were set based on the emanation spectrometry consequences, alone to each sample. The extremum count was set at 30,000 and the? ex was 333 nanometer. The ice chest was set at approx -28 A ; deg ; C for the sensing system. Both switches for the power supply were turned on. CD900 Test on the desktop was opened. Then right clicked on Initialise all devices to avoid mistake reports the flag must be to the full closed. The F900 package started. Choose position and nF lamp set-up . The force per unit area in the lamp chamber was checked to be about 0.35-0.50 saloon. Then the visible radiation was switched on. The lamp frequence was set to 40 kilohertz. The electromotive force was approx. 7 V and the lamp sensor had an strength of approx. 3. When ready, pressed use so near . A diffuse milklike solution was inserted as a standardization technique. The excitement and emanation wavelengths were set harmonizing to earlier consequences. Scan started and saved to a file. The life-times of the samples were calculated by opening the saved life clip spectra, pressing informations on the control panel and taking exponential tantrum . There are two alternate adjustment processs ( I ) reconvolution tantrum and ( two ) tail Fit. Tail tantrum was used because these samples were expected to hold longer life-times than the heavy hydrogen lamp ( approx. 1 N ) . The samples were placed in a chamber for analysis. 2.4 Photocatalysis 2.4.1 Photocatalysis of synthesised samples utilizing a 60 W visible radiation bulb The photocatalytic debasement of the organic pollutant impersonator, methylene blue was determined utilizing the Perkin Elmer Lambda 900 UV/VIS/NIR Spectrometer between 400 800 nanometer. Approx. 0.06 g of calcined pulverization was placed in a glass beaker with a stirring saloon where methylene blue ( 50 milliliter, ten 10-5 M ) was added. The sample was placed on a magnetic stirring home base and was covered with a bluish filter, guaranting that merely light above 420 nanometers would make the sample. Equilibration was reached between the sample and the organic pollutant by stirring the suspension in darkness for 30 min. After 30 min a 3 milliliter aliquot was taken and placed in a labelled extractor tubing and was stored off in a dark imperativeness. The bluish filter was replaced over the sample and the 60 W light bulb was switched on. After 30 min, a 3 milliliter aliquot was removed, this procedure was repeated for 2 H and 30 min taking a 3 milliliter aliquot every 30 min while guaranting the bluish filter was replaced each clip. The samples were non cloudy as the pulverization was denser than the methylene bluish solution ; therefore they were nt centrifuged for 8 min like Degussa P25. The debasement of methylene blue was measured utilizing the UV/vis spectrometer. On the desktop Lambda 900 selected. Methylene bluish absorbs at approx. 456 nm hence scan scope set between 500 800 nanometer. Baseline rectification and car nothing were both done. Ordinate manner was set to A ( optical density ) . Choosing the sample icon computing machine requests the figure of samples, ( 5 in this instance, over 2.5 hour ) . computing machine now prompts each sample in order. Consequences saved and imported into Excel plotting optical density against wavelength ( nm ) . A 1st order kinetic secret plan, plotting Ln ( Ao/A ) against clip ( s ) , where A is the optical density at times t and A0 is the optical density at times zero of the consequences, generated. The incline of this line was equal to the rate of debasement and was subbed into equation 2.3. Equation 2.3 To cipher the rate of debasement t=ln2k where K is the photocatalytic rate of debasement of methylene blue by the sample. Methylene blue was prepared from the stock solution ( 10-3M ) in the research lab and was prepared in a 1:100 ratio of methylene blue: deionised H2O giving methylene blue ( 10-5 M ) . Chapter 3: Consequences and Discussion 3. Consequences and Discussion 3.1 Synthesis TiO2 and TiO2 modified with Ru ( bpy ) 32+ at concentrations runing from 0.1 to 2.0 % was prepared via the sol gel procedure and so calcined at 400, 600 and 800 A ; deg ; C. An issue arose environing the readying of TiO2 colloidal suspension gels. The documented experimental stated that acetic acid had to be added to the TTIP which resulted in cloping issues. It was found that by adding TTIP to the acetic acid the synthesis worked better, from here the original experimental was followed. After drying at 100 A ; deg ; C a white and ruddy orange solids were collected, declarative of TiO2 and TiO2-Ru ( bpy ) 32+ . Approximately 3 g of stuff was obtained after drying expect at 2.0 % Ru ( bpy ) 32+ as 1/5 of the declared volume was used in the synthesis to cut down Ru ( bpy ) 32+ ingestion. When calcined the unmodified TiO2 samples remained white going shinier as the temperature increased. The modified TiO2 samples turned gray black with increased burden and temperature. 3.2.1 Differential Scanning Calorimeter DSC analysis was carried out on TiO2, TiO2 modified with Ru ( bpy ) 32+ and untreated Ru ( bpy ) 32+ pulverization. The consequences in figure 3.4 show that in both samples incorporating TiO2, a loss of H2O and acetic acid at 100 A ; deg ; C occurred. A larger H2O extremum was seen for the modified TiO2 sample as it was non to the full dried when analysed. The 330 A ; deg ; C is declarative of the formless to crystalline formation of TiO2. The presence of Ru ( bpy ) 32+ did non impact the crystal growing of TiO2 up to 500 A ; deg ; C as the formless to crystalline stage alteration remained the same in both modified and unmodified TiO2. 3.2.2 X-ray diffraction ( XRD ) XRD analysis was carried out on all samples prepared. This determined what signifier of TiO2 was present at each temperature. The consequences showed that anatase formed at 400 and 600 A ; deg ; C and pure rutile was present at 800 A ; deg ; C for the unmodified TiO2 samples. Figure 3.5 below high spots this. The burdens were presumed to moo to see ruthenium extremums under XRD, nevertheless at TiO2-2 % Ru ( bpy ) 32+ Ru extremums were detected. There was no literatre published on the effects of temperature on Ru ( bpy ) 32+ but on comparing of the extremums, the 2 % lading complement that of the criterion calcined to 600 A ; deg ; C. The signifier at these high temperatures is still unknown. A communications paper found that metallic ruthenium17 signifiers at 600 A ; deg ; C but no farther publication was made on it. Figure 3.5 XRD exemplifying anatase, rutile and Ru extremums found in TiO2 modified with 2 % Ru ( bpy ) 32+ at 600 A ; deg ; C. The significance of this consequence was that all other samples analysed at 600 A ; deg ; C calcination, modified and unmodified were strictly anatase but at this lading rutile extremums were beggining to organize. Baring in head that the anatase to rutile transmutation occurs at 700+ A ; deg ; C, analysis was initated on 0, 0.1 and 0.5 % burdens at 700 A ; deg ; C and 800 A ; deg ; C. As expected all 800 A ; deg ; C samples were 100 % rutile. The samples investigated at 700 A ; deg ; C resulted in an addition in the % rutile nowadays at increased burdens. A similar consequence was seen when TiO2 was doped with Ag and Fe. Ghosh et al highlighted a similar happening in Fe doped TiO2 sample.18 This discovery meant that the presence of Ru ( bpy ) 32+ was impacting crystal growing at 700 A ; deg ; C. A new revalation as the DSC consequences confirmed earlier that the dye was holding no consequence on the crystal growing up to 500 A ; deg ; C. Aceleration in the anatase to rutile transmutation is important as it means that TiO2 is being converted into its most stable signifier, rutile earlier. It is possible that the samples can be tuned to accomplish a peculiar concentration of each TiO2 signifier. Figure 3.6 Shows the important acceleration in crystal growing at 700 A ; deg ; C clearly. 3.2.3 Raman Spectroscopy Samples were analysed under Raman at 514.5 and 785 nanometer. Merely TiO2 extremums were obtained at 514.5 nanometers, most likely due to the low burden of Ru ( bpy ) 32+ in the stuff or that at higher temperatures the composite had decomposed. The Peaks observed at 400 and 600 A ; deg ; C were declarative of anatase, and rutile at 800 A ; deg ; C. These consequences correlated the XRD consequences for the same temperatures. After correspondence with research workers specialised in Ru composites it was agreed that the laser line of 514.5 nanometer was deficient for Ru sensing and that a laser line of 785 nanometers would be more suited. Burning of the sample was suspected which would suppress sensing. Experiment as to what % filter to utilize was carried out by traveling from 100 to 25 to 10 to 1 % . It was found that by cut downing the filter to 1 % the sample was less likely to fire. This determination was made based on exposing the sample to the optical maser at the assorted filters for several seconds, so exchanging back on the microscope to find if the sample had burned or non. The grade to which the dye was firing became cl

Hierarchy of Roman Offices in the Cursus Honorum

Hierarchy of Roman Offices in the Cursus Honorum The order of advancement through elected offices (magistracies) in Republican Rome was known as the cursus honorum. The sequence of offices in the cursus honorum meant that an office couldnt be skipped, in theory. There were exceptions. There were also optional offices that could be steps along the cursus honorum. Sequence Leading to the Top Office of Consul A Roman male of the upper classes became Quaestor before he could be elected Praetor. He had to be elected Praetor before Consul, but the candidate need not have been either an Aedile or Tribune. Other Requirements for Progress Along the Cursus Honorum The Quaestor candidate had to be at least 28. Two years had to elapse between the end of one office and the beginning of the next step on the cursus honorum. The Roles of the Cursus Honorum Magistrates and the Senate Originally, the magistrates sought the advice of the Senate when and if they wished. Over time, the Senate, which was made up of the magistrates past and present, insisted on being consulted. Insignia of the Magistrates and Senators Once admitted to the Senate, the magistrate wore a wide purple stripe on his tunic. This was called the latus clavus. He also wore a special scarlet colored shoe, the calceus mulleus, with a C on it. Like the equestrians, senators wore gold rings and sat in the reserved front row seats at performances. The Meeting Place of the Senate The Senate usually met in the Curia Hostilia, north of the Forum Romanum and facing the street called the Argiletum. [See Forum Map.] At the time of Caesars assassination, in 44 B.C., the Curia was being rebuilt, so the Senate met in Pompeys theater. The Magistrates of the Cursus Honorum Quaestor: The first position in the cursus honorum was Quaestor. The term of Quaestor lasted a year. Originally there were two Quaestors, but the number increased to four in 421, to six in 267, and then to eight in 227. In 81, the number was increased to twenty. The Assembly of the thirty-five tribes, the Comitia Tributa, elected Quaestors. Tribune of the Plebs: Annually elected by the plebeian section of the Assembly of the Tribes (Comitia Tributa), known as the Concilium Plebis, there were originally two  Tribunes of the Plebs, but by 449 B.C., there were ten. The Tribune held great power. His physical person was sacrosanct, and he could veto anyone, including another Tribune. A Tribune could not, however, veto a dictator. The office of Tribune was not a mandatory stage of the cursus honorum. Aedile:  The Concilium Plebis elected two Plebeian Aediles each year. The Assembly of the thirty-five tribes or Comitia Tributa elected two  Curule Aediles annually. It was not necessary to be an Aedile while following the cursus honorum. Praetor:  Elected by the Assembly of the Centuries, known as the Comitia Centuriata, the Praetors held office for a year. The number of Praetors increased from two to four in 227; and then to six in 197. In 81, the number was increased to eight. Praetors were accompanied by two lictores within the confines of the city. The lictores carried the ceremonial rods and ax or fasces that could, in fact, be used to inflict punishment. Consul:  The Comitia Centuriata or Assembly of the Centuries elected 2 Consuls annually. Their honors included being accompanied by 12 lictores and wearing the toga praetexta. This is the top rung of the cursus honorum. Sources Marsh, Frank Burr; revised by H.H. Scullard. A History of the Roman World From 146 to 30 B.C. London: Methuen Co. Ltd., 1971.www.theaterofpompey.com/rome/reviewmagist.shtml Regular Magistracies of the Roman Republic From T. S. R. Broughtons Magistrates of the Roman Republic.The Procedure of the Senate, by A. G. Russell.  Greece Rome, Vol. 2, No. 5 (Feb., 1933), pp. 112-121.Jona Lendering Cursus Honorum

The Characteristics of the Good Prince (Leader) Essay

The Characteristics of the Good Prince (Leader) - Essay Example As the word Machiavellian suggests, a modern prince needs to be cunning, deceitful and crude if need be (Niccolo, 2010). The Machiavellian claim answers the question of whether one should love or fear a leader. Machiavelli states that it would be better to be loved and feared, but the two cannot exist at ago (Niccolo, 2010). He says that it is, therefore, better to be feared because leaders need complete obedience from their people for them to completely govern. The vulnerability of the subject towards punishment makes him submit to the leader (Niccolo, 2010). With fear, people only reluctantly trust the leader hoping that the leader is concerned with their good. Some leaders prove their care for their people hence eventually gain trust and love whereas others are feared throughout their leadership. He says that love contains many rules, most of which may be broken by selfish men. Fear, on the other hand, lives long because people are afraid of punishment that would befall them when they rebel (Niccolo, 2010). This aspect of fear and love is important in todays politics whereby leaders tend to pursue either love or hatred especially during elections. Despite the fact that no leader is perfect, people fail to concentrate on the bad side of a good leader and only se his good side. A leader should however see to it that his people do not hate him. Hatred would only lead to the princes failure. He states that the peoples allegiance is a stronger shield than a fortress (Niccolo, 2010). The love of the people gradually grows to trust, which is of most advantage to the leader. Trust makes it easier for the prince to carry on executions without objection. The leader himself will feel less fear of being overthrown because of the mutual trust. A good leader should also ensure that he gains the support of his people. Unless he achieves this, it is easy for jealous competitors to overthrow the

Business law ( write a short story using the therms) Essay

Business law ( write a short story using the therms) - Essay Example is case had a condition precedent attached to it since the buyer of furniture is demanding that the furniture should be imported by no later than May 01, 2010 at London Port. If Simons Co. fails to export the requested items by the required date than Ajax Co. is declared free from making any payment since the condition precedent has not been fulfilled. Simons Co. being a multinational organization has the ability to borrow funds from international sources. It had initially borrowed fund amounting to $950,000 from Bank of England. So within the contract, Simons Co. contracts Ajax Co. to pay $950,000 to Bank of England if the contract is executed. The Bank of England is basically the creditor beneficiary in this case. On the other hand, by the virtue of law of assignment Ajax Co. transfers his rights to receive the furniture to Magna Co. which is a local dealer of furniture. Simon Co. was facing buoyant demand in its country and had tough time in meeting the contract. So it further refines the terms and condition of the contract with Ajax Co. that it will delegate its responsibility of manufacturing the required amount of furniture to another local corporation since it might not be able to meet the request due to its limited manufacturing capacity. The contract was finalized and it had all the explicit conditions mentioned and in case if some ambiguous terms are found than court will rule the decision against the party who has drafted the

Police Accountability Essay Example | Topics and Well Written Essays - 1750 words

Police Accountability - Essay Example As the paper declares abusive police behavior is conceived of as antithetical to the functioning of a modern, free society and the public has a natural right to seek arrests in instances of police abuse. Seeking to understand police accountability presently in place in Canada, the following essay will explore the mechanisms to keep police officers subject to the law which they are charged with upholding. What are the police accountability mechanisms presently in Canada and are these mechanisms effective? With the theme of exploring this question with an eye to the ramifications of police accountability and 21st century, the following now turns to an exploration of police accountability in the Canadian context. According to the discussion findings as stated above, police accountability is essential to the functioning of a modern and free democratic society. Accordingly, Canadian society is based upon the notion that power rests with the people in that elected officials are subservient to the electorate. This is the basis of modern liberal democratic governance and the tenets which frame the ideas of Canadians vis-Ã  -vis their elected officials are also relevant with respect to the security of the state. Similarly, those who are entrusted with upholding the law are subject to the stipulations of the criminal justice system and are held accountable for their actions in the pursuit of fairness, justice and equality. In the Canadian context, police officers are accountable to the wider public through a variety of mechanisms which are in place to ensure that police officers remain subject to the law while they seek to uphold it.

Zen Buddhism Essay Example for Free

Zen Buddhism Essay Buddhism has grown from the flowing of a single man in his path to nirvana to a religion that spans the globe and has shaped many cultures. This paper will first present the history of Buddhism and the life of the man known as Buddha. Then, the fundamental teachings of Buddhism will be discussed. Finally, the unique aspects of Zen Buddhism will be examined. History of Buddhism and Life of Buddha Although the truths are ultimately unknown, Michael Molloy, in Experiencing the World’s Religions (2013), presented the details of the life of Siddhartha Gautama, the man who would come to be known as Buddha. Around 500 B.C.E., Siddhartha was born to a prince of the Shakya tribe in modern day Nepal. Siddhartha’s mother died a week after childbirth, leaving him in the care of a father whom, on the advice of a sage, ensured Siddhartha would leave an extremely sheltered but pleasant life. Upon Siddhartha’s first excursion into the world, he witnessed suffering and was so moved by it that he left home and went in search of a path to enlightenment. After attempting to gain insight through asceticism, Siddhartha rejected this way as inadequate and sought a path based on moderation instead. Legend speaks of Siddhartha meditating under a tree now knows as a Bodhi tree, resolved to not leave until he had reached the understanding that he sought. At dawn, Siddhartha achieved nirvana or enlightenment and became known as Buddha. Buddhism is a rejection of the Hindu gods, Vedic priesthood, and rituals. Fundamental Teachings of Buddhism Among Buddha’s teachings are three primary concepts: The Three Marks of Reality, The Four Noble Truths, and The Noble Eightfold Path. The Three Marks of Reality   Buddha taught that all reality bore three characteristics; Change, No Permanent Identity, and Suffering (Molloy, 2013). Change is the idea that all of reality, every facet and as a whole, is in constant flux, and turmoil. No permanent identity is the belief that all of reality, both living and non-living, has a permanent aspect; that no soul or spirit exists that resists the changes of time. The last mark of reality is suffering, the concept that, because reality is ever changing, all contentment most pass and bring misery in its wake. The Four Noble Truths The first truth is that to live is to suffer, meaning that in every stage of life, change will occur and that change will bring suffering and discontent. The second truth is that suffering comes from desire. This truth states that desire, in all of its aspects, binds mankind to illusions that reality will disprove and replace with suffering. The third truth is that to end suffering, one must end desire; that suffering will not cease when all desires are met, only when all desires are extinguished. Lastly, the fourth truth taught by Buddha is that release from suffering is possible and can be attained by following the noble eightfold path (Molloy, 2013). T he Noble Eightfold Path According to Molloy (2013), the Noble Eightfold Path is a set of eight practices, taught by Buddha, to allow the follower to â€Å"to face life objectively, to live kindly, and to cultivate inner peace† (pg. 134). The first part of the Path is Right Understanding, to recognize and understand the 3 marks of reality. The second part is Right Intention, maintaining a purity of thought and motives, untainted by desires and emotions. The third part of the path is Right Speech, the understanding that what if said can cause harm and that lies, exaggerations, and harsh words must be avoided. The fourth, Right Action, is to remember that there is already enough suffering in the world and that the actions of the follow should not contribute to that pain, even to animals. The fifth part is Right Work that one’s work does not cause additional suffering, even to one’s self. The sixth, Right Effort, is the understanding that, while maintaining moderation in one’s life, steps to improve should be taken when they can. The seventh step is Right Meditation that the follower uses meditation to examine the  depths of reality. Finally, the last part is the Right Contemplation, actively striving to obtain states of blissful inner peace in one’s life. Buddha did not teach that the eight steps were like a ladder, taken one after another, but all at the same times, to lead his followers closer to the state of nirvana. Zen Buddhism As the school of Mahayana developed, and traveled to China, it experienced pushback from its complex rituals and ceremonies. This pushback led to the forming of the school of Chan, with a simplification of Buddhist life and focus on singular meditation. As the school of Chan traveled to Japan, it further blended and developed into Zen Buddhism. Zen Buddhism developed it simplicity by examining the meditation and enlightenment of Buddha directly, and the teaching if Buddha that ritual does not directly lead to enlightenment. Zen has blended with Japanese society, and culture, influencing thought, art, and expression. Because of the influence of Zen Buddhism, Japanese arts have developed around the ideals of simplicity, practicality, and emptiness. An example of the ideals of Zen Buddhism can be found in the practice of the koan. A koan is a question that cannot be easily answered with logic, meditated on and answered in a way that demonstrated the understanding of the principle lesson of the koan, rather than explaining it (Molloy, 2013). Conclusion The paper has examined the life of Siddhartha Gautama, the man known as Buddha. Also, the Buddha’s teachings concerning reality and achieving inner peace have been described. Finally, the uniqueness of the school of Zen Buddhism has been explained. Reference Molloy, M. (2013). Experiencing the world’s religions: Tradition, challenge, and change (6th ed.). New York, NY: McGraw-Hill Inc..